Large heterometallic coordination cages with gyrobifastigium-like geometry

Giacomo Cecot; Bassam Alameddine; Stéphanie Prior; Rita De Zorzi; Silvano Geremia; Rosario Scopelliti; Farzaneh T. Fadaei; Euro Solari; Kay Severin

doi:10.1039/c6cc06066h

Large heterometallic coordination cages with gyrobifastigium-like geometry

Giacomo Cecot
, Bassam Alameddine
, Stéphanie Prior
, Rita De Zorzi
, Silvano Geremia
, Rosario Scopelliti
, Farzaneh T. Fadaei
, Euro Solari
, Kay Severin

Gulf University for Science and Technology

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Large (M_w > 10 kDa) heterometallic coordination cages with gyrobifastigium-like geometry are obtained by using metalloligands with sterically demanding Fe^II clathrochelate cores and four divergent pyridyl groups. Upon reaction with cis-blocked Pt^II and Pd^II complexes, MII8L₄ cages are formed. The gyrobifastigium geometry of these cages is in contrast to the barrel-like structures which are typically observed for metallasupramolecular assemblies with M₈L₄ stoichiometry.

Original language	English
Pages (from-to)	11243-11246
Number of pages	4
Journal	Chemical Communications
Volume	52
Issue number	75
DOIs	https://doi.org/10.1039/c6cc06066h
State	Published - 2016

Funding Agency

Kuwait Foundation for the Advancement of Sciences

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10.1039/c6cc06066h

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title = "Large heterometallic coordination cages with gyrobifastigium-like geometry",

abstract = "Large (Mw > 10 kDa) heterometallic coordination cages with gyrobifastigium-like geometry are obtained by using metalloligands with sterically demanding FeII clathrochelate cores and four divergent pyridyl groups. Upon reaction with cis-blocked PtII and PdII complexes, MII8L4 cages are formed. The gyrobifastigium geometry of these cages is in contrast to the barrel-like structures which are typically observed for metallasupramolecular assemblies with M8L4 stoichiometry.",

author = "Giacomo Cecot and Bassam Alameddine and St{\'e}phanie Prior and Zorzi, \{Rita De\} and Silvano Geremia and Rosario Scopelliti and Fadaei, \{Farzaneh T.\} and Euro Solari and Kay Severin",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6cc06066h",

language = "English",

volume = "52",

pages = "11243--11246",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "75",

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TY - JOUR

T1 - Large heterometallic coordination cages with gyrobifastigium-like geometry

AU - Cecot, Giacomo

AU - Alameddine, Bassam

AU - Prior, Stéphanie

AU - Zorzi, Rita De

AU - Geremia, Silvano

AU - Scopelliti, Rosario

AU - Fadaei, Farzaneh T.

AU - Solari, Euro

AU - Severin, Kay

PY - 2016

Y1 - 2016

N2 - Large (Mw > 10 kDa) heterometallic coordination cages with gyrobifastigium-like geometry are obtained by using metalloligands with sterically demanding FeII clathrochelate cores and four divergent pyridyl groups. Upon reaction with cis-blocked PtII and PdII complexes, MII8L4 cages are formed. The gyrobifastigium geometry of these cages is in contrast to the barrel-like structures which are typically observed for metallasupramolecular assemblies with M8L4 stoichiometry.

AB - Large (Mw > 10 kDa) heterometallic coordination cages with gyrobifastigium-like geometry are obtained by using metalloligands with sterically demanding FeII clathrochelate cores and four divergent pyridyl groups. Upon reaction with cis-blocked PtII and PdII complexes, MII8L4 cages are formed. The gyrobifastigium geometry of these cages is in contrast to the barrel-like structures which are typically observed for metallasupramolecular assemblies with M8L4 stoichiometry.

UR - https://www.scopus.com/pages/publications/84987811478

U2 - 10.1039/c6cc06066h

DO - 10.1039/c6cc06066h

M3 - Article

AN - SCOPUS:84987811478

SN - 1359-7345

VL - 52

SP - 11243

EP - 11246

JO - Chemical Communications

JF - Chemical Communications

IS - 75

ER -

Large heterometallic coordination cages with gyrobifastigium-like geometry

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